Effie and Haymitch
It turns out that that kiss was not originally in the script, and that Woody Harrelson actually had a little crush on Elizabeth Banks, so he decided to go for the opportunity to kiss her. Luckily, it ended up working well for the characters as well.
Effie And Haymitch
Top Gun
In the iconic scene from classic film Top Gun, Charlie (who is played by Kelly McGillis) admits that she has feelings for Maverick, played by none other than Tom Cruise. Charlie makes it clear that she does not want anyone to know about her feelings, when suddenly Maverick kisses her.
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Top Gun